Determination of antimony in natural water samples by graphite-furnace AAS with silver used as a chemical modifier.
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منابع مشابه
Graphite Furnace AAS: Application of Reduced Palladium as a Chemical Modifier
Chemical modification techniques are widely used in graphite furnace atomic absorption spectrometry (GFAAS). Palladium is a very effective chemical modifier and can be used to stabilize many elements to several hundred degrees higher than the temperatures possible with current methods [1-9]. Of the elements tested, the greatest temperature shifts are achieved for the semi-metallic elements such...
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A large-volume (100 microl) injection-ETAAS with W-treated PG furnace combined with a phosphate modifier was applied to the determination of unpolluted levels of Cd in tap, snow and river-water samples. The limit of detection of 1.1 ng l(-1) was observed for a 4 w/v% NH4H2PO4 modifer. Matrix interference studies were tested for major ion species well found in fresh water. The direct determinati...
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In this work a rapid and selective procedure for separation and preconcentration of lead(Pb2+) before determination by electrothermal atomic absorption spectrometry (ETAAS) wasdeveloped. The procedure is based on the electrodeposition on a graphite probe modified withpalladium. The lead was deposited from acetate buffer solution at pH 5.5. Various parameters,such as pH of solutions, deposition ...
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Methods for direct determination of antimony and chromium in human serum by Graphite Furnace Atomic Absorption Spectrometry (GF AAS) were proposed in this work. The samples were diluted in 1:1 with nitric acid 1% v/v and Triton® X-100 0.1% v/v. The optimization of the instrumental conditions was done using a multivariate approach. A factorial design (2) was employed to investigate the tendency ...
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An amoniumvanadate plus sodium molybdate mixed modifier Graphite Furnace Atomic Absorption Spectrometric method has been developed for determination of traces of lead in drinking water. The concentration of lead in the sample is obtained by direct comparison to linear working graph prepared from aqueous standards in the modifier medium, The results indicate the better performance of the pro...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1997
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.46.639